Married at First Sight: Channel 4, 9pm
In an exploration as to whether science can determine true love, three couples are about to marry - the catch being they've never met their new other half until the big day.
This experiment has nailed down 1,500 applicants into three 'compatible' couples based on anthropology, psychology, and theology. This week, we meet the soon-to-be married couples.
Beauty & The Beast: Watch, 9pm
Vincent and Catherine are back as season three of the hit CBS drama premieres in the UK tonight.
Several weeks have pasted since Gabe was defeated, and Vincent and Catherine now adjust to their new lives after making their relationship public - but things don't stay sweet for long.
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Love Island: Live: ITV2, 10pm
It's elimination time again for the islanders, as Caroline Flack reveals who will be next to leave the competition.
Meanwhile, former Celebrity Love Island star Paul Danan returns to tell Caroline what he thinks of this year's contestants.
Breaking Bad: Spike, 11:10pm
Re-live 'Felina' again, as the last episode of Vince Gilligan's critically-acclaimed drama finally premieres on free-to-air television in the UK.
Walt returns to Albuquerque much to the disgust of everyone, as he's the last person anyone wants to see. Meanwhile, tensions run high as Walt and Jesse reunite.
