Marvel's Agents of SHIELD: Channel 4, 8pm
After last week's shock ending, this episode picks up exactly where it left off.
Not knowing who to trust, there is a frantic scramble to understand who is a friend and who is a foe. Agent Coulson's team are being attacked from all sides and with their lives now on the line, it's a matter of shoot first and ask questions later.
As the Clairvoyant's identity is finally revealed, so is the true nature of one of SHIELD's best agents.
The Blacklist: Sky Living, 9pm
The Pavlovich brothers are back and according to Red, they're planning their next hit. Xao Ping Li, a specialist involved in a chemical weapons project known as White Fog, is their next target.
What to Read Next
While efforts are made to try and track the brothers, a confrontation between Tom and Liz arises. The result is Liz further doubting Red and wondering what he has been hiding from her.
The Trip to Italy: BBC Two, 10pm
Rob Brydon and Steve Coogan continue to tour Italy, and this week Coogan's assistant Emma joins the duo in Rome.
After visiting the Keats-Shelley Memorial House museum, the group move on to a restaurant, where Brydon and Coogan showcase their best impersonations of Marlon Brando's Don Corleone from The Godfather.
It's then that Emma announces the reason for her visit. She has some news for the two of them.
Da Vinci's Demons: Fox, 10pm
In this episode, the cast is split and each member has their own adventure.
On board his borrowed slave ship and sailing across the Atlantic without the aid of maps, Leonardo experiences a mutiny from his crew.
Meanwhile, Lorenzo is accompanied on his undercover trip to Naples, and Lucrezia makes her way to the Vatican in the hope of attending a secret meeting.
